VS 2010 and .NET 4.0 training materials are available.

Visual Studio 2010 and .NET Framework 4 Training Kit - October Preview is released . Including materials on the following new or updated technologies:

* C # 4.0
* Visual Basic 10
* F #
* Parallel Extensions
* Windows Communication Foundation (WCF)
* Windows Workflow
* Windows Presentation Foundation (WPF)
* ASP.NET 4
* Windows 7
* Entity Framework
* ADO.NET Data Services
* Managed Extensibility Framework (MEF)
* Visual Studio Team System
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Includes presentations, source codes, videos and documentation. Download from here (93.3 MB).

PS : a more detailed description of the content is available here .